15. Diisobutylaluminum hydride (DIBAL-H) can be used to carry out which of the following conversions?
a) Ester to aldehyde
b) Carboxylic acid to ester
c) 2 moles of alcohol to ketone
d) Aldehyde to carboxylic acid
c) Ester to ketones

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the   per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:                   1 - α               α               α           = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

=  

or,

or,   = (at v = 1l)

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:               (1 - α)/0.5           α/0.5         α/0.5       = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

or,  

=  

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

the law of conservation of mass states that in a chemical reaction, the total mass of reactants is equal to the total mass of products. because atoms are only rearranged in a chemical reaction, there must be the same number of sodium atoms and chlorine atoms in both the reactants and products

l dont know l am s sorry