The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2 HgCl2 + C2O42- 2 Cl- + Hg2Cl2 + 2 CO2 Experiment [HgCl2] [C2O42-]o, M Initial Rate
1 0.124 0.115 1.61E-5
2 0.248 0.015 3.23E-5
3 0.124 0.229 6.40E-5
4 0.248 0.229 1.28E-4
1) Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n.
2) From these data, the rate constant is M-2s-1?

Explanation:

2 HgCl₂ + C₂O₄²⁻   =  2 Cl⁻ + Hg₂Cl₂ + 2CO₂

1 )

Rate of reaction

             [HgCl₂]        [C₂O₄²⁻ ]           Rate  

1 .              .124             .115               1.61 x 10⁻⁵

2 .             .248             .115             3.23 x 10⁻⁵

3 .              .124             .229              6.4 x 10⁻⁵

4 .              .248             .229            1.28 x 10⁻⁴

comparing 1 and 3 , when concentration of HgCl₂ remains constant and concentration of C₂O₄²⁻  becomes twice , rate becomes 4 times so rate is proportional to square of concentration of C₂O₄²⁻  .

Hence n = 2

comparing 1 and 2 , when concentration of HgCl₂ becomes twice  and concentration of C₂O₄²⁻  remains constant  , rate becomes 2 times so rate is proportional to simply  concentration of C₂O₄²⁻  .

Hence m = 1

Putting the data of  1 in the rate equation found

 1.61 x 10⁻⁵ = k x .124 x  .115²

k = 11.3 x 10⁻⁴ M⁻² s⁻¹

considering the question as per the attachment

here we can see that the radon nuclide has 222 as the atomic mass number and 86 as the atomic number.

when it undergoes nuclear fission it gives polonium which has atomic mass number as 218 and atomic number will be 84 along with a helium nucleus which has 4 atomic mass number and 2 as its atomic number.

222 = 218 + 4 (atomic mass number)

86 = ? + 2; therefore ? = 86-2 = 84.

the atomic mass number of polonium will be 84.