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Chemistry, 06.05.2020 05:43 amberwithnell12512
At atmospheric pressure, acetone (1) and chloroform (2) form an azeotrope that boils at 64.6 °C and has a mole fraction of acetone in the liquid of 0.335. The saturation vapor pressures of acetone and chloroform at 64.6 °C are 1.31 and 0.98 atm, respectively.(i)Find the activity coefficients of acetone and chloroform at the azeotrope.(ii)Find the value for GE in kcal/mol.(iii)Using the calculated values, find the composition of vapor over liquid at 64.6 C that contains 12 mol% acetone. Use Van laar equation.(iv)Find the total pressure of the solution at the above condition. Given: van Laar model is as follows RTx1x2GE=1Bx1+1Ax2n1=A(1+ABx1x2)2n2 =B(1+BAx2x1)2A=n1[1+x2x1n2n1]2B=n2[ 1+x1x2n1n2
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At atmospheric pressure, acetone (1) and chloroform (2) form an azeotrope that boils at 64.6 °C and...
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