Assume you mix 100.0 mL of 200 M CsOH with 50.0 mL 0f 0.400 M HCl in a coffee cup calorimeter. A reaction occurs. The temperature of both solutions before mixing was 22.50 °C, and it rises to 24.28 °C after the acid-base reaction. What is the enthalpy change for the reaction per mole of CaOH? Assume densities of the solutions are all 1.00 g/mL and the specific heat capacities of the solutions are 4.2 J/gK

The enthalpy change for the reaction per mole of CsOH is -56.1 kJ/mol

Explanation:

Step 1: Data given

Volume of a CsOH solution = 100.0 mL

Molarity of a CsOH solution = 0.200 M

Volume of HCl solution = 50.0 mL

Molarity of HCl solution = 0.400M

The temperature of both solutions before mixing was 22.50 °C, and it rises to 24.28 °C after the acid-base reaction.

Density = 1.00 g/mL

Specific heat = 4.2 J/gK = 4.2 J/g°C

Step 2: The balanced equation

CsOH + HCl → CsCl + H2O

Step 3: Calculate the energy

Q = m*c*ΔT

⇒with Q = the heat transfer = TO BE DETERMINED

⇒with m = the mass of the solution = (100+ 50 mL) * 1.00 g/mL = 150 grams

⇒with c = the specific heat of the solution = 4.2 J/g°C

⇒with ΔT = The change of temperature = T2 - T1  = 24.28 °C - 22.50 °C = 1.78 °C

Q = 150 grams * 4.2 J/g°C * 1.78 °C

Q = 1121.4 J

Step 4: Calculate moles CsOH

Moles CsOH = molarity CsOH * volume CsOH

Moles CsOH = 0.200M * 0.100 L

Moles CsOH = 0.0200 moles

Step 5: Calculate  the enthalpy change for the reaction per mole of CsOH

ΔH is negative since this is an exothermic reaction

ΔH = -Q/moles

ΔH = -1121.4 J / 0.0200 moles

ΔH = -56070 J/mol = -56.1 kJ/mol

The enthalpy change for the reaction per mole of CsOH is -56.1 kJ/mol

according to the u.s. department of agriculture, the label of "certified organic" comes with a set of highly regulated standards for environmental stewardship and resource conservation. some of these include maintenance and improvement of soil quality, prevention of ground and surface water contamination, greenhouse gas regulation, encouragement of biodiversity and conservation of water and energy (see references 1). organic practices integrate natural methods such as mulching, plant diversity, native and adapted plants, crop rotation and the introduction of beneficial insects to control pests without synthetic pesticides.

environmental implications of pesticides

synthetic pesticides ensure high crop yields. while effective in achieving this goal, pesticides contaminate soil, air, ground and surface water, as well as the plants and animals that come into contact with these contaminated sources. freshwater and marine organisms are particularly susceptible to pesticides through agricultural runoff. pesticides also reduce soil fertility (necessitating the use of synthetic fertilizers) and can travel far from the original source, contaminating water and air hundreds of miles from the location of application (see references 2).

health implications of organics

although a subject of particular debate, many recent findings show that organic food is healthier than conventionally grown food. according to the usda, an extensive european union-funded study found that organically grown foods contain more beneficial compounds, such as the vitamins and antioxidants needed to combat many diseases (see references 5). organic milk, meat and eggs are regulated to ensure they are free of hormones administered to conventional livestock and poultry.

health implications of pesticides

pesticides affect human health in three ways: through skin contact, inhalation and ingestion. acute and long-term exposure to pesticides can cause serious health problems for farmers who apply them. the majority of other people are affected by drinking contaminated water and eating contaminated marine life (see references 3). pesticides have been linked to neurological disorders, endocrine and reproductive disorders, immune system deficiencies and cancer. according to the world health organization, acute pesticide poisoning (app) is responsible for significant annual mortality, especially in developing nations (see references 4).

other important considerations

not every small farm or business owner can afford the costly certification process required to be considered "certified organic," even if the farm is not using chemicals. "transitional" farms include those that once used chemicals and are now transitioning to organic-only production. in addition, though organic farming methods offer obvious environmental benefit, an organic apple shipped from around the world creates a different set of environmental problems. locally grown food (particularly locally grown, organic food) is key in sustainable food production.