Benzene was treated with a set of unknown reagents. Using the spectral data below, draw the most likely product and select the most likely set of reagents. 1H NMR: See spectra below. 13C NMR: 142 ppm, 128 ppm, 128 ppm, 125 ppm, 38 ppm, 24 ppm, and 13 ppm. MS: There is no detectable M+2 peak. IR: Peaks observed at 3100 cm-1 and at 2900 cm-1. There is NO absorbance near 1700 cm-1.

Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. an industrial chemist studying this reaction fills a 25.0l tank with 4.5 mol of sulfur dioxide gas and 4.5 mol of oxygen gas at 30.°c. he then raises the temperature, and when the mixture has come to equilibrium measures the amount of sulfur trioxide gas to be 1.4 mol. calculate the concentration equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. round your answer to 2 significant digits.