It is quite common for a solid to change from one structure to another at a temperature below its melting point. For example, sulfur undergoes a phase change from the rhombic crystal structure to the monoclinic crystal form at temperatures above 95C. Which form of sulfur has the more ordered crystalline structure (has the smaller positional probability)?

in 1783 cavendish was working with his hydrogen gas and found that when he burned it and condensed the vapor it was water. this was very significant since it disproved the greek theory of elements completely since water was not a simple substance but the product of two gases. it was lavoisier who hearing of the experiment gave cavendish's gas the name hydrogen ("water-producer") and added that hydrogen burned by combining with oxygen and that water was a hydrogen-oxygen combination.

explanation:

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.