Chemistry, 08.04.2020 00:01 madisontrosclair2
Part B.4. As a result of adding the NaOH titrant too rapidly and an unwillingness to allow the pH meter to equilibrate before reading its pH, the stoichiometric point is ill defined. As a result of this technique error,
a. will the molar mass of the weak acid be reported as too high or too low? Explain.
b. will the pK_a of the weak acid be reported as too high or too low? Explain.
Answers: 2
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Consider the reduction reactions and their equilibrium constants. cu+(aq)+eโโฝโโโcu(s)pb2+(aq)+2eโโฝโโโpb(s)fe3+(aq)+3eโโฝโโโfe(=6.2ร108=4.0ร10โ5=9.3ร10โ3 cu + ( aq ) + e โ โฝ โ โ โ cu ( s ) k =6.2ร 10 8 pb 2 + ( aq ) +2 e โ โฝ โ โ โ pb ( s ) k =4.0ร 10 โ 5 fe 3 + ( aq ) +3 e โ โฝ โ โ โ fe ( s ) k =9.3ร 10 โ 3 arrange these ions from strongest to weakest oxidizing agent.
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Part B.4. As a result of adding the NaOH titrant too rapidly and an unwillingness to allow the pH me...
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