Chemistry, 12.02.2020 18:31 gracebuffum

At 298 K, the osmotic pressure of a glucose solution (C6H12O6 (aq)) is 12.1 atm. Calculate the freezing point of the solution. The density of the solution is 1.034 g/mL.

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Answer from: Jasten

The freezing point of solution is -0.974°C

Explanation:

To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

$\pi=iMRT$

where,

$\pi$ = osmotic pressure of the solution = 12.1 atm

i = Van't hoff factor = 1 (for non-electrolytes)

M = molarity of solute = ?

R = Gas constant = $0.0821\text{ L atm }mol^{-1}K^{-1}$

T = temperature of the solution = 298 K

Putting values in above equation, we get:

$12.1atm=1\times M\times 0.0821\text{ L.atm }mol^{-1}K^{-1}\times 298K\\\\M=\frac{12.1}{1\times 0.0821\times 298}=0.495M$

This means that 0.495 moles of glucose is present in 1 L or 1000 mL of solution

To calculate the mass of solution, we use the equation:

$\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}$

Density of solution = 1.034 g/mL

Volume of solution = 1000 mL

Putting values in above equation, we get:

$1.034g/mL=\frac{\text{Mass of solution}}{1000mL}\\\\\text{Mass of solution}=(1.034g/mL\times 1000mL)=1034g$

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

Moles of glucose = 0.495 moles

Molar mass of glucose = 180.16 g/mol

Putting values in above equation, we get:

$0.495mol=\frac{\text{Mass of glucose}}{180.16g/mol}\\\\\text{Mass of glucose}=(0.495mol\times 180.16g/mol)=89.18g$

Depression in freezing point is defined as the difference in the freezing point of pure solution and freezing point of solution.

The equation used to calculate depression in freezing point follows:

$\Delta T_f=\text{Freezing point of pure solution}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

Or,

$\text{Freezing point of pure solution}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}$

where,

Freezing point of pure solution = 0°C

i = Vant hoff factor = 1 (For non-electrolytes)

K_f = molal freezing point elevation constant = 1.86°C/m

$m_{solute}$ = Given mass of solute (glucose) = 89.18 g

$M_{solute}$ = Molar mass of solute (glucose) = 180.16 g/mol

$W_{solvent}$ = Mass of solvent (water) = [1034 - 89.18] g = 944.82 g

Putting values in above equation, we get:

$0-\text{Freezing point of solution}=1\times 1.86^oC/m\times \frac{89.18\times 1000}{180.16g/mol\times 944.82}\\\\\text{Freezing point of solution}=-0.974^oC$

Hence, the freezing point of solution is -0.974°C

Answer from: Quest

(newtons first law)

conservation of momentum law states :

momentum before collision = momentum after collision

momentum p (kg-m/s)= mass * velocity

say moving car=1 000 kg, velocity = 10 m/s then p = 1 000*10= 10 000 kg-m/s

say still car = 2 000 kg, velocity = 0 m/s then p = 2 000* 0 = 0 kg-m/s

total momentum prior to collision = 10 000 + 0 = 10 000 kg-m/s

momentum after collision = 10 000 kg-m/s

mass now = 1 000 kg+2 000 kg = 3 000 kg

10 000 = 3 000 kg* velocity m/s

10 000/3 000 = velocity

3.33 m/s = velocity after collision

an impulse is a force applied over time , momentum is exclusive of external forces and a perfect collision is implied

Answer from: Quest

0.88m hope i am correct : )

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At 298 K, the osmotic pressure of a glucose solution (C6H12O6 (aq)) is 12.1 atm. Calculate the freez...

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