Chemistry, 13.01.2020 02:31 ayanajames0928

Can someone on five and six i am at a loss on how to solve it

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Answer from: MuntazerMehdi9746

Q5.

a} Yes , All Cl2 get eliminated by adding 170 g of sodium thiosulfate .

b) There excess of Sodium thiosulfate by 2.637 g

Q6.

a) Mass = 162 g Sodium bicarbonate

b)Volume of Ammonia remain after the reaction = 0.086 x 24.8 = 1.60 L

Explanation:

Points to be considered :

There is a difference between STP and SATP :

STP = Standard Temperature and Pressure (273.15 K and 1 atm)

1 mole of gas at STP = 22.4 L

SATP = Standard Ambient Temperature and Pressure (293.15 K and 1 atm)

1 mole of gas at SATP = 24.8 L

$moles = \frac{Given\ mass}{Molar\ mass}$

Number of moles of gas at SATP :

$moles = \frac{Given\ Volume}{24.8L}$

Q5.

First, calculate the number of moles of Cl2 and thiosulfate present in the reaction :

Volume of Cl2 = 105 L

Moles of Cl2 =

$moles = \frac{Given\ Volume}{24.8}$

$moles = \frac{105}{24.8}$

Moles of Cl2 in Reaction medium = 4.2338 mole

Mass of Sodium thiosulfate = 170 g

Molar mass of thiosulfate = 158.11 g/mol (theoretical value)

$moles = \frac{170}{158.11}$

= 1.075

Moles of Sodium Thiosulfate in Reaction medium = 1.075 mole

To check whether the given moles of Cl2 and sodium thiosulfate satisfy theoretical values :

Consider the Given reaction and apply law of conservation of mass

$4Cl_{2}+Na_{2}S_{2}O_{3}+5H_{2}O\rightarrow 2NaHSO_{3}+8HCl$

$Na_{2}S_{2}O_{3}$ = sodium thiosulfate

This equation indicates ,

4 moles of Cl2 require = 1 mole of sodium thiosulfate

1 mole of Cl2 require =

$\frac{1}{4}$ of sodium thiosulfate = 0.25

4.2338 mole of Cl2 should need = 0.25 x 4.2338

= 1.058 mole of sodium thiosulfate

Required Thiosulfate = 1.058 mole

But,

Moles of Sodium Thiosulfate in Reaction medium = 1.075 mole

So , extra moles of Sodium Thiosulfate is present in the reaction by

= 1.075 - 1.0589 = 0.0166 mol

Molar mass of sodium thiosulfate = 158 .11 g/mol

$Mass =0.166\times 158.11$

= 2.637 g

a} .Yes , All Cl2 get eliminated by adding 170 g of sodium thiosulfate .

b) There excess of Sodium thiosulfate by 2.637 g

Q6.

Volume of ammonia = 50.0 L

Moles of Ammonia ,

$moles = \frac{Given\ Volume}{24.8L}$

$moles = \frac{50}{24.8L}$

= 2.016 moles

Moles of CO2 =

Mass of CO2 = 85.0 g

Molar mass = 44 g/mol

$moles = \frac{Given\ mass}{Molar\ mass}$

$moles = \frac{85.0}{44}$

= 1.932 mol of CO2

Now check the law of conservation of mass :

$NaCl + NH_{3} + CO_{2} +H_{2}O\rightarrow NaHCO_{3} +NH_{4}Cl$

According to above equation ,

1 mole of CO2 Needs = 1 mole of NH3

1.93 mol of CO2 need = (1 x 1.93) mol

1.93 mol of CO2 need = 1.93 mol of ammonia

Available ammonia = 2.016 mol

So Ammonia is in excess by:

= 2.016 - 1.93 mol

= 0.086 mol

Volume at SATP is calculated by

$V =mole\times 24.8$

Volume of Ammonia remain after the reaction = 0.086 x 24.8

= 2.1104 L

= 2.10 L

CO2 is the limiting reagent and governs the product formation :

Molar mass of NaHCO3 = 84.007 g/mol

1 mole of CO2 Needs = 1 mole of NaHCO3 = 84.007

1.93 mol of CO2 need = 1.93 x 84.007 mol

= 162.133 g of Sodium bicarbonate

= 162 g Sodium bicarbonate

Note : The answers are present in rounded figures .

Answer from: Quest

For cyclohexane compounds drawn in a chair conformation: -axial bonds are vertical -equatorial bonds are parallel to two bonds within the ring. thus, as i assume the chair conformation is drawn: -the x group is in an axial position, as are the five other vertical bonds. -three axial bonds are on the top face of the ring -the other three axial bonds are on the bottom face the position of the second substituent on each ring carbon is equatorial. gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other. drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1. click this link and watch some academic videos that may you more understand the topic

Answer from: Quest

C: plants and animals

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