Exam page 3 answer the following two questions a paper chromatography experiment was conducted on a mixture of amino acids including aspartic acid (asp), glutamic acid (glu), histidine (his), leucine (leu), phenylalanine (phe) and proline (pro). the following rf values were determined: asp (0.245), glutamic (0.275), his (0.295), leu (0.745), phe (0.685) and pro (0.445). in the experiment, a colored spot for unknown amino acid "x" was found centered at a distance 61 mm from the start line when the solvent line had travelled 82 mm. (1) show the calculation for the rf value for amino acid "x" and (2) identity amino acid "x". 61mm/82mm=.744, this corresponds to leu 0.745 2.) it is ba(hso4)2 , h cannot be detected which of the following is the formula of unknown #1 which gives the following sem spectrum. explain your answer. bs2o3 so3br ba(hso4)2

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

Use the drop-down menus to answer each question. which runner finished the 100 m race in the least amount of time? which runner stopped running for a few seconds during the race? at what distance did anastasia overtake chloe in the race?

7. using your knowledge of colligative properties explain whether sodium chloride or calcium chloride would be a more effective substance to melt the ice on a slick sidewalk. use 3 – 4 sentences in your explanation. 8. when a 2.5 mol of sugar (c12h22o11) are added to a certain amount of water the boiling point is raised by 1 celsius degree. if 2.5 mol of aluminum nitrate is added to the same amount of water, by how much will the boiling point be changed? show all calculations leading to your answer or use 3 – 4 sentences to explain your answer. 9. if 5.40 kcal of heat is added to 1.00 kg of water at 100⁰c, how much steam at 100⁰c is produced? show all calculations leading to an answer. 10. the freezing of water at 0⁰c can be represented as follows: h2o (l) ↔ h2o(s) the density of liquid water is 1.00 g/cm3. the density of ice is 0.92 g/cm3. in 3 – 4 sentences explain why applying pressure causes ice to melt.