Can someone answer question 1 and 2

Iknow #2 is d. i just need to know why

100 grams of molten lead (600°c) is used to make musket balls. if the lead shot is allowed to cool to room temperature (21°c), what is the change in entropy (in j/k) of the lead? (for the specific heat of molten and solid lead use 1.29 j/g⋅°c; the latent heat of fusion and the melting point of lead are 2.45 × 104 j/kg and 327°c, respectively.)

Inside a flashbulb, oxygen surrounds a thin coil of magnesium. when the flashbulb is set off, a chemical reaction takes place in which magnesium combines with oxygen to form magnesium oxide. which of the chemical equations matches the reaction above? a. mg + o2 mgo2 + energy b. 2mg + o mg2o + energy c. 2mg + o2 2mgo + energy d. mg + o mgo + energy