What are the limitations of litmus paper and phenolphthalein indicators? name to other indicators that can be used that do not have such limitations

Here's what I find.

Explanation:

An indicator is usually is a weak acid in which the acid and base forms have different colours. Most indicators change colour over a narrow pH range.

(a) Litmus

Litmus is red in acid (< pH 5) and blue in base (> pH 8).

This is a rather wide pH range, so litmus is not much good in titrations.

However, the range is which it changes colour includes pH 7 (neutral), so it is good for distinguishing between acids and bases.

(b) Phenolphthalein

Phenolphthalein  is colourless in acid (< pH 8.3) and red in base (> pH 10).

This is a narrow pH range, so phenolphthalein is good for titrating acids with strong bases..

However, it can't distinguish between acids and weakly basic solutions.

It would be colourless in a strongly acid solution with pH =1 and in a basic solution with pH = 8.

(c) Other indicators  

Other acid-base indicators have the general limitations as phenolphthalein. Most of them have a small pH range, so they are useful in acid-base titrations.

The only one that could serve as a general acid-base indicator is bromothymol blue, which has a pH range of 6.0 to 7.6.

the enthalpy of formation of water is given as -285.8kj/mol, which states that the enthalpy of formation is negative.

negative enthalpy of formation indicates that the heat is released during the reaction process. the heat is released from reaction to the surroundings the enthalpy is expressed with a negative sign with the energy given out in the reaction process.

the formation of water takes place by giving out heat which is -285.8 kj/mol.

definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.