The vaporization of 1 mole of liquid water (the system) at 100.9°c, 1.00 atm, is endothermic. h2o(l)+40.7kj --> h2o(g) assume that at exactly 100.0°c and 1.00 atm total pressure, 1.00 mole of liquid water and 1.00 mole of water vapor occupy 18.80 ml and 30.62 l, respectively.

c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.