Which of the following would not be a clear indication of a chemical change

I believe the answer is "After adding two substances together a new order is detected" because nearly all of the other answers suggest a chemical change has taken place. The reason I say "almost" is because answer two and four results in bubbles forming so the answer cannot be both. The only one to not clearly show a chemical change has occurred is the last answer.

the density of gold = 19.3 g/cm3

the relation between density and mass and volume is

density = mass / volume

given :

mass of gold = 13 g

density = 13g / volume = 19.3

volume = 13 /19.3 = 0.67 cm^3

thus volume of gold nugget = 0.67 cm^3