If a sample of gas occupies 400 ml at a pressure of 800 mm hg, what will be it’s volume if the pressure is reduced to 700 mm hg

We have to calculate volume of gas at 700 mm Hg pressure.

The answer is 457.14 ml.

The pressure can be calculated by using Boyle's law. At constant temperature, for a given mass of an ideal gas pressure is inversely related to volume.

As per Boyle's law, P₁V₁ = P₂V₂, where P is pressure and V is volume of gas.

Given, P₁= 800 mm Hg, V₁= 400 ml and P₂= 700 mm Hg, V₂=?

800 X 400 = 700 X V₂

So, V₂= (800X400)/700 = 457.14 ml

chemical energy is stored in the chemical bonds of atoms and molecules. it can only be seen when it is released in a chemical reaction. when chemical energy is released, the substance from which the energy came is often changed into an entirely different substance.

this chemical reaction releases energy in the form of light and heat. chemical energy is the potential energy stored in the arrangement of atoms within molecules. breaking chemical bonds requires energy, while forming new chemical bonds releases energy.

the atp molecule can store energy in the form of a high energy phosphate bond joining the terminal phosphate group to the rest of the molecule. in this form,energy can be stored at one location, then moved from one part of the cell to another, where it can be released to drive other biochemical reactions.

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol