Explain the difference between heat and temperature.

The difference  between heat and temperature is that heat is a type of temperature and temperature is the measure of heat. Hope this helps.

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.