Considering simple atomic transitions, describe the origin of the ‘selection rules’. illustrate with one example. then, describe how such rules may be ‘broken’ when transitions occur in a crystal. for instance, how will they change when spin-orbit coupling in the p levels and octahedral ligand crystal fields are taken into account?

Oerstman, inc. uses a standard costing system and develops its overhead rates from the current annual budget.the budget is based on an expected annual output of 120,000 units requiring 480,000 direct labor hours.(practical capacity is 500,000 hours)annual budgeted overhead costs total $772,800, of which $556,800 is fixed overhead.a total of 119,300 units, using 478,000 direct labor hours, were produced during the year.actual variable overhead costs for the year were $260,400 and actual fixed overhead costs were $555,450.required: 1. compute the fixed overhead spending variance and indicate if favorable or unfavorable.2. compute the fixed overhead volume variance and indicate if favorable or unfavorable.